Journal
ORGANIC LETTERS
Volume 8, Issue 18, Pages 4141-4144Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol061763f
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Highly efficient synthesis of meso, meso-dibromo doubly and triply fused diporphyrins has been achieved through a powerful oxidative coupling mediated by AuCl3-AgOTf combination. In addition, palladium-catalyzed debromination of meso-bromoporphyrins has been developed. This debromination protocol enables employment of bromine as a protecting group for the reactive meso-position of porphyrins.
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