Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 420, Issue 1-2, Pages 175-181Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2005.10.047
Keywords
ternary alloy; quaternary alloy; mixing enthalpy; geometric model; Miedema's theory
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A method to extrapolate the thermodynamic properties of quaternary alloys from constitutive binary systems is presented. The method is based on Nbedema's theory, and the asymmetry of thermodynamic properties of constitutive binary alloys is considered in the present model. The dependence of asymmetric constituent on the choice in Toop model has been overcome. This method has been applied to calculate the enthalpies of formation for ternary alloys. In the present work, the proposed method is used to calculate the mixing enthalpies of Al-Cu-Ni-Zr quaternary alloys and its constitutive subsystems. The good agreement between calculation and experimental data indicates that the present method is reasonable for predicting the thermodynamic properties of multi-component system. (c) 2005 Elsevier B.V. All rights reserved.
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