4.5 Article

Nonpolar, polar, and associating solutes in ionic liquids

Journal

JOURNAL OF PHYSICAL CHEMISTRY B
Volume 110, Issue 34, Pages 16816-16818

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jp063603r

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The existence of microphase segregation between polar and nonpolar domains in ionic liquids changes the way in which solvation can be understood in these media. Here, we perform a structural analysis on the solvation of nonpolar, polar, and associating solutes in imidazolium-based ionic liquids, where this novel way of understanding their nature as microsegregated solvents is correlated with their ability to interact with different species in diverse and complex ways.

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