Investigating ebullition in a sand column using dissolved gas analysis and reactive transport modeling

Ebullition of gas bubbles through saturated sediments can enhance the migration of gases through the subsurface, affect the rate of biogeochemical processes, and potentially enhance the emission of important greenhouse gases to the atmosphere. To better understand the parameters controlling ebullition, methanogenic conditions were produced in a column experiment and ebullition through the column was monitored and quantified through dissolved gas analysis and reactive transport modeling. Dissolved gas analysis showed rapid transport of CH(4) vertically through the column at rates several times faster than the bromide tracer and the more soluble gas CO(2), indicating that ebullition was the main transport mechanism for CH(4). An empirically derived formulation describing ebullition was integrated into the reactive transport code MIN3P allowing this process to be investigated on the REV scale in a complex geochemical framework. The simulations provided insights into the parameters controlling ebullition and show that, over the duration of the experiment, 36% of the CH(4) and 19% of the CO(2) produced were transported to the top of the column through ebullition.