Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 348, Issue 14, Pages 1908-1918Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200606075
Keywords
carbon dioxide fixation; copolymerization; green chemistry; homogeneous catalysis; ligand design; terpolymerization
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For the alternating copolymerization of CO2 and cyclohexene oxide, a variety of zinc acetate complexes with new aminoimidoacrylate ligands has been synthesized and tested as catalysts. All complexes catalyzed the reaction and structure-activity investigations revealed that the highest activities and selectivities were reached when the ligand's aromatic rings were 2,6-substituted by alkyl groups of different size (isopropyl versus methyl) and when the ligand backbone embodied an electron-withdrawing cyano group. Furthermore, these complexes catalyzed the terpolymerization of CO2, cyclohexene oxide and lactide to give poly(cyclohexyl carbonate-co-lactide) and the composition of the polymer was adjustable by the monomer feed.
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