Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 71, Issue 18, Pages 7110-7112Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo061160h
Keywords
-
Categories
Funding
- NIGMS NIH HHS [GM 54051] Funding Source: Medline
Ask authors/readers for more resources
Addition of lithium acetylides prepared from 1-pentyne, phenylacetylene, and trimethylsilylacetylene to diverse N-tert-butanesulfinyl ketimines affords a range of alpha, alpha-dibranched propargyl sulfinamides in generally good yields (up to 87%) and with high diastereoselectivities (up to > 99: 1). Acidic cleavage of the tert-butanesulfinyl group provides the free alpha, alpha-dibranched propargylamines.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available