4.8 Article

Attraction between like-charged walls: Short-ranged simulations using local molecular field theory

Journal

PHYSICAL REVIEW LETTERS
Volume 97, Issue 9, Pages -

Publisher

AMERICAN PHYSICAL SOC
DOI: 10.1103/PhysRevLett.97.097801

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Effective attraction between like-charged walls mediated by counterions is studied using local molecular field (LMF) theory. Monte Carlo simulations of the mimic system given by LMF theory, with short-ranged Coulomb core interactions in an effective single particle potential incorporating a mean-field average of the long-ranged Coulomb interactions, provide a direct test of the theory, and are in excellent agreement with more complex simulations of the full Coulomb system by Moreira and Netz [Eur. Phys. J. E 8, 33 (2002)]. A simple, generally applicable criterion to determine the consistency parameter sigma(min) needed for accurate use of the LMF theory is presented.

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