4.7 Article

Two 3D supramolecular architectures from zinc hydrogen aconitate 1D polymers

Journal

INORGANIC CHEMISTRY COMMUNICATIONS
Volume 9, Issue 9, Pages 915-919

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2006.05.031

Keywords

zinc(II); 1D polymer; 3D supramolecular architecture; H-bond; stacking; crystal structure

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The reaction of Zn(NO3)(2)center dot 3(H2O) with trans-aconitic acid, in presence of chelating Lewis bases, leads to the formation of the 1D polymers [Zn(N-N)(LH)] center dot nH(2)O, where LH3 = trans-aconitic acid, 1 : N-N = 1,10-phenanthroline (phen), n = 1, 2 : N-N = 2,2'-bipyridine (bpy), n = 2. 3D supramolecular assemblies are constructed through H-bonding and stacking interactions. (C) 2006 Elsevier B.V. All rights reserved.

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