Journal
CHEMISTRY LETTERS
Volume 35, Issue 9, Pages 1028-1029Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2006.1028
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Formation of chiral polydiacetylene (PDA) film using circularly polarized light (CPL) was demonstrated for the first time. Commercially available achiral derivative of diacetylene was used to prepare the vacuum evaporated monomer film and it was polymerized using ultra-violet CPL. Chiral source was only CPL, and the irradiation of left- and right-CPL definitely yielded opposite chiral polymer.
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