Anodic properties of tin oxides with pyrochlore structure for lithium ion batteries

Mixed tin oxides, M2Sn2O7 (M = Y, Nd), with cubic pyrochlore structure were synthesized and characterized by X-ray diffraction and SEM. Galvanostatic cycling versus Li metal in the voltage range, 0.005-1.0 V at the current density of 60 mA g(-1) showed that the first-discharge capacities are 913 and 722 mA hg(-1) whereas the first-charge capacities are 350 and 265 (+/- 3) mA hg(-1), for M = Y and Nd, respectively. The corresponding number of moles of recyclable Li are 3.4 and 3.2 for M = Y and Nd. Crystal structure destruction occurs during the first-discharge leading to the formation of nano-particles of Sn-metal and finally Li4.4Sn in a matrix of Li-M-O. After 50 cycles, both compounds showed a capacity-retention of 89 (+/- 1)% of the 10th cycle reversible capacity. The coulombic efficiency is similar to 98%. The average charge and discharge voltages in both compounds are 0.5 and 0.25 V, respectively. Cyclic voltammograms complement the galvanostatic results and showed that a good operating voltage range is 0.005-1.0 V. The electrodic performances of M2Sn2O7 have been compared with those exhibited by other crystalline ternary tin oxides. (c) 2006 Elsevier B.V. All rights reserved.