Journal
ORGANIC LETTERS
Volume 8, Issue 19, Pages 4331-4333Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol061741t
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- NIGMS NIH HHS [GM066153, R01 GM066153-19A1, R01 GM066153] Funding Source: Medline
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A new method for the synthesis of nitriles is described. As a complement to the classic cyanation of aryl halides using cyanide sources and a transition metal catalyst, the palladium-catalyzed cross-coupling of thiocyanates with boronic acids in the presence of copper(I) thiophene-2-carboxylate (CuTC) affords nitriles in good to excellent yields.
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