Journal
ORGANIC LETTERS
Volume 8, Issue 19, Pages 4191-4194Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol061246x
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A phosphoramidite of the perylene bisimide dye was synthesized as a DNA building block that allows incorporation of this chromophore as an artificial nucleoside surrogate either at the 5'-terminus or at internal positions of duplex DNA. The internally incorporated perylene bisimide chromophore shows strong interactions with the DNA base stack; the 5'-terminally attached perylene bisimide is able to induce dimerization of two whole DNA duplexes.
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