Journal
ORGANIC LETTERS
Volume 8, Issue 19, Pages 4367-4370Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0617749
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A new family of air- and moisture-stable phosphine-phosphoramidite ligands (PEAPhos) has been prepared from commercially available and inexpensive ( S)-alpha-phenylethylamine through a two- or three-step transformation and successfully applied in the rhodium-catalyzed enantioselective hydrogenations of a variety of substrates, in which up to 99.9% ee was obtained for all of these kinds of substrates.
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