Diffusion coefficient of DMF in acrylic fiber formation

A H2O/dimethyl formamide (DMF) mixture was used as the coagulation bath of wet-spun process for acrylic fibers. Diffusion coefficient of DMF in the protofibers prepared by acrylonitrile/acrylamide copolymers was determined. It has been found that diffusion coefficient of DMF outflow of the protofibers prepared by acrylonitrile/acrylamide copolymers synthesized by solution polymerization is highest compared with those of acrylonitrile/acrylamide copolymers synthesized by H2O/DMF mixture suspension polymerization and aqueous suspension polymerization. With an increase of copolymer concentration in the dope, diffusion coefficient of DMF decreases continuously. Diffusion coefficient of DMF increases along with the bath temperature, but the changes in diffusion coefficient values are less prominent as temperature goes beyond 55 degrees C. When DMF concentration in the coagulation bath was 50%, the value of the diffusion coefficient of DMF was minimal. Diffusion coefficient of DMF increases along with jet stretch minus ratio increase. (c) 2006 Wiley Periodicals, Inc.