4.7 Article

Preparation of allyl sulfoxides by palladium-catalyzed allylic alkylation of sulfenate anions

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 71, Issue 19, Pages 7449-7454

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo061359u

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Palladium-catalyzed allylic alkylation of sulfenate anions, generated from beta-sulfinylesters by retro-Michael reaction, can take place under biphasic conditions. This new reaction provides a simple, mild, and efficient route to allyl sulfoxides in good yields.

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