Journal
INORGANIC CHEMISTRY
Volume 45, Issue 19, Pages 7566-7568Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic0609002
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Funding
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0910761] Funding Source: National Science Foundation
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A trigonal nanosized carboxylate ligand, 1,3,5-tris[4'-carboxy(1,1'-biphenyl-4-yl)] benzene (TCBPB), has been synthesized and applied in the construction of porous metal-organic frameworks (MOFs). A solvothermal reaction of TCBPB and a zinc salt in the presence of pyridine produces 1, an unstable MOF consisting of a tetrazinc secondary building unit (SBU) with labile terminal ligands. Changing pyridine to a noncoordinating base in the assembly procedure affords 2, a stable MOF with permanent porosity containing an octazinc SBU without labile terminal ligands.
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