Journal
INORGANIC CHEMISTRY
Volume 45, Issue 19, Pages 7584-7586Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic060989b
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A coordination polymer, [Cu-5(piv)(5)](n) (piv = pivalate), was prepared by a thermal decomposition method. The unit cell of the crystal structure consisted of one right-handed helical chain and one left-handed helical chain, which were formed by an alternation of Cu-I ions and carboxylate (O-C-O) groups. This chain possessed a pseudo-5(3) screw axis; the second-order structure was suggested to be realized by a balance between the cuprophilicity and a steric effect of the tert-butyl groups.
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