Journal
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume 2, Issue -, Pages -Publisher
BEILSTEIN-INSTITUT
DOI: 10.1186/1860-5397-2-18
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The asymmetric aza-Diels-Alder reaction of chiral imines with Danishefsky's diene in chiral ionic liquids provides the corresponding cycloadduct with moderate to high diastereoselectivity. The reaction has proved to perform better at room temperature in ionic liquids without either Lewis acid catalyst or organic solvent. Chiral ionic liquids are recycled while their efficiency is preserved.
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