Journal
TETRAHEDRON
Volume 62, Issue 38, Pages 8982-8987Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2006.07.012
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The electrophilic beta-alkylation of secondary alcohols with primary alcohols is accomplished by a hydrogen autotransfer process catalyzed by RUCl2(DMSO)(4). The reaction can produce either simple alkylated secondary alcohols or alpha,beta-unsaturated ketones with good to excellent results just by choosing the appropriate starting secondary alcohol (methyl or longer chain secondary alcohol, respectively), as well as quinolines (by using 2-aminobenzyl alcohol). (c) 2006 Elsevier Ltd. All rights reserved.
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