Journal
BIOPHYSICAL CHEMISTRY
Volume 123, Issue 2-3, Pages 113-121Publisher
ELSEVIER
DOI: 10.1016/j.bpc.2006.04.014
Keywords
pyridoxal phosphate; cyanoacetylene; diacetylene; carbon monoxide; hydrogen; water; phosphoric acid
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A set of chemical reactions is proposed to account for the formation of pyridoxal phosphate, Vitamin B-6, from a primeval atmosphere composed of cyanoacetylene, diacetylene, carbon monoxide, hydrogen, water, and a phosphoric acid. The reactions have been shown to be feasible from the overall enthalpy changes in the ZKE approximation at the HF and MP2/6-31G* level. (c) 2006 Elsevier B.V. All rights reserved.
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