Journal
TETRAHEDRON LETTERS
Volume 47, Issue 39, Pages 7107-7111Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2006.07.105
Keywords
ruthenium; catalyst; cyclocotrimerization; 2-pyridone; pyrimidine-2,4-dione
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A neutral rhodium(I) complex, 'RhCI(PPh3)(2)' generated by the combination of [RhCl(C2H4)(2)](2) with a fourfold amount of PPh3, effectively catalyzed the cyclocotrimerization of alkynes (1) and isocyanates (2) to give 2-pyridones (3) and/or pyrimidine-2,4-diones (4), selectively, by controlling the molar ratio of alkynes (1) and isocyanates (2). (c) 2006 Elsevier Ltd. All rights reserved.
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