Journal
TETRAHEDRON
Volume 62, Issue 39, Pages 9280-9288Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2006.06.079
Keywords
hydroarylation; Claisen rearrangement; pyran; thiopyran; dihydrothiopyran; chromene
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We have designed and synthesized several basic and novel fused ring heterocycles by intramolecular hydroarylation with an efficiency and scope to develop intermediates of potential value. This method demonstrated consistent performance with arene-ene and arene-yne substrates of diverse structural features, including propargyl ethers, allyl thioethers, and propargyl thioethers resulting in 6-endo products. (c) 2006 Elsevier Ltd.. All rights reserved.
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