4.5 Article

Catalytic hydrosilylation of carbonyl compounds with cationic oxorhenium(V) salen

Journal

ORGANOMETALLICS
Volume 25, Issue 20, Pages 4920-4923

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/om060503z

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High-valent cationic oxorhenium(V) salen complexes efficiently catalyze the reduction of carbonyl compounds by organosilanes under mild, open-flask conditions. Good to excellent yields of silyl-protected alcohols are obtained in one step, and a variety of functional groups are compatible.

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