Journal
ORGANIC LETTERS
Volume 8, Issue 20, Pages 4549-4552Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol061767k
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Small carbosilane dendrons in which a closo-carborane is located at the focal point have been prepared by a sequence of steps involving hydrosilylation and reduction reactions. These compounds are used as scaffolds for peripheral functionalization with styrene, chlorovinylstyrene, or suitable carboranes, while keeping the C-cluster - Si (C-c-Si) bond. Modification of the core by reduction of the carborane with Mg/BrCH2CH2Br was also achieved.
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