Journal
ORGANIC LETTERS
Volume 8, Issue 20, Pages 4489-4492Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol061751u
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The tandem cycloisomerization-hydroalkoxylation of various homopropargylic alcohols in the presence of an alcohol and a dual catalyst system, consisting of a gold precatalyst and a Bronsted acid, provides an efficient route to tetrahydrofuranyl ethers under mild reaction conditions. The reaction can be carried out in various solvents, including alcohol, with both terminal and internal alkynes as the substrate.
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