4.5 Article

Acoustical studies of some Schiff bases in 1,4-dioxane and dimethylformamide at 318.15 K

Journal

CHINESE JOURNAL OF CHEMISTRY
Volume 24, Issue 10, Pages 1327-1331

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.200690247

Keywords

Schiff base; 1,4-dioxane; DMF; ultrasonic velocity; density; viscosity

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From experimental data of density, viscosity and ultrasonic velocity, the various acoustical properties, such as specific impedance (Z), isentropic compressibility (K-s), Rao's molar sound function (R-m), the van der Waals constant (b), molar compressibility (W), intermolecular free length (L-f), relaxation strength (r), internal pressure (pi), free volume (V-f), solvation number (S-n) etc., were calculated for three Schiff bases in 1,4-dioxane and dimethylformamide (DMF) at 318.15 K. The results are interpreted in terms of molecular interactions occurring in the solutions.

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