4.7 Article

Hydrothermal synthesis, crystal structures and characterizations of a novel 3D metal phosphonate:: Mg0.5Cd[O3PCH(OH)CO2]

Journal

INORGANIC CHEMISTRY COMMUNICATIONS
Volume 9, Issue 10, Pages 999-1001

Publisher

ELSEVIER
DOI: 10.1016/j.inoche.2006.06.015

Keywords

metal phosphonates; crystal structure; hydrothermal synthesis; cadmium; magnesium

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A novel cadmium and magnesium phosphonate compound Mg0.5Cd[O3PCH(OH)CO2] (1) has been synthesized by hydrothermal reaction at 110 degrees C and characterized by single-crystal X-ray diffraction as well as with infrared spectroscopy, elemental analysis and thermogravimetric analysis. The structure of 1 comprises CdO6 octahedra and MgO6 octahedra connected by [O3PCH(OH)CO2](3-) to form 3D framework with one-dimensional channel system in the a-axis direction. (C) 2006 Elsevier B.V. All rights reserved.

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