Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 348, Issue 15, Pages 2063-2067Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200600236
Keywords
amination; diarylmethylamine; gold; indium; Lewis acid
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The Lewis acid-mediated direct amination of benzylic alcohols is described, providing various benzylic amine derivatives in good yields under mild and environmentally benign conditions. Among the different Lewis acids tested, gold(III) proved to be the catalyst of choice for both chemical (yield, conversion) and practical reasons (a filtration over a silica pad is generally sufficient to obtain the corresponding benzylic amine in analytically pure form).
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