Potentiometric membrane sensor based on 6-(4-nitrophenyl)-2,4-diphenyl-3,5-diaza-bicyclo[3.1.0] hex-2-ene for detection of Sn(II) in real samples

A Sn2+ ion-selective electrode which was prepared with a polymeric membrane based on 6-(4-nitrophenyl)-2,4-diphenyl-3,5-diazabicyclo[3.1.0]hex-2-ene (NDDBH) as a ionophore. Effects of experimental parameters such as membrane composition, nature and amount of plasticizer, the amount of additive and concentration of internal solution on the potential response of Sn2+ sensor were investigated. The electrode exhibited a Nernstian slope of 28.8 +/- 1.1 mV/decade of Sn2+ over a concentration range of 1.0 x 10(-5) to 1.0 x 10(-1) M of Sn2+ in an acidic solution (pH 1). The limit of detection was 4.0 x 10(-6) M. The results show that this electrode can be used in ethanol media until 20% (v/v) concentration without interference. It can be used for more than 6 weeks without any considerable divergence in the potentials. The proposed membrane electrode revealed very good selectivity for Sn(II) ions over a wide variety of other cations and could be used in acidic media. The standard electrode potentials were determined at different temperatures and used to calculate the isothermal coefficient of the electrode. The stability constant (log K-s) of the Sn(II)-ionophore complex was determined at 25 degrees C by potentiometric titration in mixed aqueous solution. It was used as indicator electrode in potentiometric determination of Sn(II) ion in real samples. (c) 2006 Elsevier B.V. All rights reserved.