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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 128, Issue 39, Pages 12829-12834Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja062868g
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General principles for designing stable highly symmetrical clusters are proposed. This approach takes advantage of both the extra stability of cage aromaticity and the good geometrical balance between the outer cage and the endohedral atom. The applicability of these design principles was confirmed by gas-phase experimental observations on group 14 element cages with endohedral Al's and also is illustrated by many literature examples of diverse systems.
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