Journal
JOURNAL OF APPLIED POLYMER SCIENCE
Volume 102, Issue 1, Pages 571-576Publisher
JOHN WILEY & SONS INC
DOI: 10.1002/app.24310
Keywords
forest fuels; thermal decomposition; kinetic model; kinetic parameters
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Decomposition of some Chinese forest fuels has been studied by means of nonisothermal thermogravimetric analysis in oxidative and inert atmosphere at low heating rates. A comparison between thermogravimetric curves obtained in air and nitrogen shows that the existence of oxygen enhances the decomposition rate and changes the mechanisms of thermal degradation. After the water evaporation, two well-defined decomposition stages have been observed in thermogravimetric curves obtained in air, which correspond to oxidative degradation of main components and oxidation of char formed. A kinetic model named two-step consecutive reaction model is developed to describe the thermal degradation process of these materials in air, and there is a good agreement between the experimental and calculated thermogravimetric and derivative thermogravimetric curves. (c) 2006 Wiley Periodicals, Inc.
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