Journal
TETRAHEDRON
Volume 62, Issue 41, Pages 9650-9654Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2006.07.077
Keywords
reduction; sulfoxides; pyridine N-oxides; dioxomolybdenum dichloride
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A novel method for the reduction of sulfoxides and pyridine N-oxides using a silane and a catalytic amount Of MoO2Cl2 in excellent yields and with a wide functional group tolerance is reported. A green protocol for this reaction was developed in water with the air-stable catalytic system PMHS/MoO2Cl2(H2O)(2). (c) 2006 Elsevier Ltd. All rights reserved.
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