Journal
ORGANIC LETTERS
Volume 8, Issue 21, Pages 4799-4801Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol061858h
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A rhodium-catalyzed multicomponent-coupling reaction has been developed that involves a cross-coupling with organohalides as part of the reaction sequence. Through several experiments toward mechanistic investigations, it has also been demonstrated that the reaction most likely proceeds via a carborhodation-oxidative addition-reductive elimination pathway, which clearly contrasts to the corresponding palladium-catalyzed processes.
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