Journal
ORGANIC LETTERS
Volume 8, Issue 21, Pages 4947-4949Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0619866
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A simple method for the direct ortho-arylation of benzoic acid amides has been developed. The palladium-catalyzed reactions proceed in trifluoroacetic acid and require the presence of stoichiometric silver acetate. This presents an alternative to the currently used ortho-lithiation strategies for the synthesis of arylated benzoic acid derivatives.
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