Journal
ORGANIC LETTERS
Volume 8, Issue 21, Pages 4887-4889Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol061955a
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[GRAPHICS] The efficient addition of bis(pinacolato)diboron to alpha,beta-unsaturated carbonyl compounds with a copper-diphosphine catalyst has been carried out. A dramatic rate acceleration of the reaction was realized by adding alcohol additives. With use of this procedure, a variety of alpha,beta-unsaturated carbonyl compounds including conjugated substrates at the acid oxidation level such as esters and nitriles were reacted to give to the corresponding beta-boryl carbonyl compounds in high yields.
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