Journal
ORGANIC LETTERS
Volume 8, Issue 21, Pages 4907-4910Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0619819
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[GRAPHICS] Platinum(II) and an unusual cationic gold( I) complex were identified as mild catalysts for the room temperature cycloisomerization or tandem hydroalkoxylation/acetal formation of unactivated internal alkynols. Under the appropriate conditions, 5-endo, 5-exo, 6-endo, and 6-exo cycloisomerization modes are all available.
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