4.5 Article

Unexpected highly chemselective anodic ortho-coupling reaction of 2,4-dimethylphenol on boron-doped diamond electrodes

Journal

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2006, Issue 20, Pages 4569-4572

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200600466

Keywords

electrochemistry; C-C coupling; oxidation; phenols; BDD electrodes

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Anodic conversion of 2,4-dimethylphenol on boron-doped diamond (BDD) electrodes under solvent-free conditions results in an unusual highly selective formation of the desired 2,2'-biphenol, representing the best electrochemical synthesis for this particular compound. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).

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