Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 71, Issue 21, Pages 8023-8027Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo061113p
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Our objectives were to develop catalytic atom-economic processes accessing and/or incorporating versatile functionality using aryl/heteroaryl acetonitriles as substrates. We report essentially solvent-free [Cp*IrCl2](2) catalyzed redox neutral processes whereby substituted acetonitriles react with primary alcohols to deliver monosubstituted aryl/heteroaryl acetonitriles in excellent yield. We further demonstrate that such processes can be achieved by conventional or microwave heating and that bis- and tris-primary alcohols are also processed efficiently.
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