Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 71, Issue 21, Pages 8320-8323Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo061507g
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As the first example for the synthesis of optically active alpha-hydroxyaldehydes and alpha-hydroxyketones in ionic liquids, we applied RTILs into L-proline catalyzed direct enantioselective alpha-aminoxylation of both aldehydes and ketones successfully. This protocol features a number of advantages, such as recycling of green solvents and chiral organocatalyst, high yields, excellent enantioselectivities, short reaction times, and broad substrate scope.
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