Journal
JOURNAL OF MEMBRANE SCIENCE
Volume 283, Issue 1-2, Pages 366-372Publisher
ELSEVIER
DOI: 10.1016/j.memsci.2006.07.007
Keywords
nanofiltration; polyelectrolytes; membranes; anions; separation
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Alternating layer-by-layer deposition of polycations and polyanions on porous substrates is a convenient and versatile method for forming high-flux nanofiltration (NF) membranes. This study compares the NF performance of four different types of multilayer polyelectrolyte membranes in Cl-/SO42- separations. Membranes were prepared using two polycations, poly(allylamine hydrochloride) (PAH) and poly(diallyldimethylammonium chloride) (PDADMAC), and two polyartions, poly(acrylic acid) (PAA) and poly(styrene sulfonate) (PSS). NF solution fluxes decreased in the order PSS/PDADMAC, PSS/PAH > PAA/PDADMAC >> PAA/PAH, which is consistent with permeability being controlled by the charge density (ionic cross-linking) in the system, as suggested previously. Interestingly, SO42- rejections were also highest for the PSS/PDADMAC system, making these membranes the most promising for Cl-/SO42- separations. In the best case (PSS/PDADMAC)(3)PSS deposited on a porous alumina support showed a 96% rejection of SO42-, a chloride/sulfate selectivity of 26, and a solution flux of 2.7 m(3)/m(2) day at 4.8 x 10(5) Pa. In a direct comparison with a commercial NF270 membrane, the (PSS/PDADMAC)(3)PSS membranes allowed a 2.7-fold higher flux along with greater passage of Cl-, but the NF270 system exhibited higher (99.5%) SO42- rejections. (c) 2006 Elsevier B.V. All rights reserved.
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