Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 12, Issue 31, Pages 7970-7977Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200600618
Keywords
iridium; luminescence; OLEDs; photochemistry; structure-property relationships
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Funding
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0949238] Funding Source: National Science Foundation
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Phosphorescent iridium(III) complexes are being widely explored for their utility in diverse photophysical applications. The performance of these materials in such roles depends heavily on their excited-state properties, which can be tuned through ligand and substituent effects. This concept article focuses on methods for synthetically tailoring the properties of bis-cyclometalated iridium(III) materials, and explores the factors governing the nature of their lowest excited state.
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