Journal
ORGANIC LETTERS
Volume 8, Issue 22, Pages 5085-5088Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol061999j
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- NCRR NIH HHS [P41 RR 0954] Funding Source: Medline
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A novel [2]-rotaxane has been prepared in which perfluoropropyl stoppers have been utilized as electronic blocking groups. To further investigate this capability, a linear compound that was precapped with perfluoropropyl groups was also prepared. This compound did not demonstrate rotaxane formation when mixed with dibenzo-24-crown-8, providing further evidence that the perfluoropropyl groups were effective electronic stoppers for the macrocycle.
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