4.5 Article

Reactions of dry arenediazionium o-benzenedisulfonimides with triorganoindium compounds

Journal

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2006, Issue 21, Pages 4884-4890

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200600527

Keywords

indium; cross-coupling; palladium; Diazo compounds

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The reaction between various arenediazonium. o-benzenedisulfonimides and triorganoindium compounds is described. Depending on the reaction conditions, it is possible to obtain biaryls (16 examples, average yield of 79%) or diaryldiazenes (18 examples, average yield of 81%). o-Benzenedi-sulfonimide can be recovered and reused to prepare additional arenediazonium o-benzenedisulfonimides. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006).

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