Journal
INORGANIC CHEMISTRY
Volume 45, Issue 22, Pages 8817-8819Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic0608997
Keywords
-
Categories
Ask authors/readers for more resources
4,6-Di-2'-pyridylpyrimidine is employed as a bis( diimine) ligand bridging two cobalt bis( dioxolene) centers. The thermally induced valence tautomeric transitions of these two metal centers are coupled through the ligand. The result is that sequential switching from high-spin Co-II to low-spin Co-III of one center, followed by the onset of switching of the other center at lower temperature, is observed in a solid amorphous thin film by IR absorption spectroscopy.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available