Journal
APPLIED SURFACE SCIENCE
Volume 253, Issue 1, Pages 322-327Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apsusc.2006.06.004
Keywords
Pr(2)O(3); LaAlO(3); spectroscopic ellipsometry; optical properties; thin films
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High-k polycrystalline Pr(2)O(3) and amorphous LaAlO(3) oxide thin films deposited on Si(0 0 1) are studied. The microstructure is investigated using X-ray diffraction and scanning electron microscopy. Optical properties are determined in the 0.75-6.5 eV photon energy range using spectroscopic ellipsometry. The polycrystalline Pr(2)O(3) films have an optical gap of 3.86 eV and a dielectric constant of 16-26, which increases with film thickness. Similarly, very thin amorphous LaAlO(3) films have the optical gap of 5.8 eV, and a dielectric constant below 14 which also increases with film thickness. The lower dielectric constant compared to crystalline material is an intrinsic characteristic of amorphous films. (c) 2006 Elsevier B.V. All rights reserved.
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