Journal
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
Volume 6, Issue 11, Pages 3338-3342Publisher
AMER SCIENTIFIC PUBLISHERS
DOI: 10.1166/jnn.2006.005
Keywords
multi-dimension; network; nano; channel; anion; inter-replacement; magnetic property
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The X-ray structure, porous and magnetic property of a self-assembled network 1 is described in detail. The single crystal X-ray analysis provides 1 as a three-dimensional network, which contains two-dimensional permanent ring forming nanoscale one-dimensional channels. The interreplacement of perchlorate and hexafluorophosphate anions in solid 1 proves its porous structure. There is somewhat strong antiferromagnetic interaction (J = -74.1 cm(-1)) between two copper(II) ions through oxalate bridge and weak antiferromagnetic interaction (J = -5.1 cm(-1)) through AEP ligand.
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