4.3 Article

Fluorimetric determination of aluminium using sequential injection analysis (SIA): State of our art and future developments

Journal

INSTRUMENTATION SCIENCE & TECHNOLOGY
Volume 34, Issue 6, Pages 619-633

Publisher

TAYLOR & FRANCIS INC
DOI: 10.1080/10739140600963830

Keywords

aluminium; fluorimetric determination; sequential injection analysis

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This paper describes some of our recent advances and proposed future work in the area of fluorimetric determination of Al using sequential injection analysis (SIA). A rapid, automated system was developed with turnover times for sample analysis of < 2 min, and attainable limits of detection of < 1 ng/mL. The method is cost-effective and highly competitive. It utilizes three different approaches: (i) molecular imprinted polymers (MIPs); (ii) micellar enhanced treatment; and (iii) renewable surface application. The merits and limitations of each approach are discussed, and the optimum conditions of analysis are presented. The overall sensitivity achieved was more than adequate for general analysis. Proposed new developments involve greater signal enhancement, and improved analytical strategy. The facility is capable of routine application, and is highly beneficial to developing countries in need of cost-effective techniques for analysis of environmental samples, body fluids, and foodstuffs.

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