Journal
KINETICS AND CATALYSIS
Volume 47, Issue 6, Pages 901-906Publisher
PLEIADES PUBLISHING INC
DOI: 10.1134/S0023158406060139
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The mechanochemical synthesis of calcium and copper ferrites has been investigated by X-ray powder diffraction, X-ray crystallography, thermogravimetric analysis, IR spectroscopy, sedimentation analysis, and chromatography. The effects of mechanical activation and heat treatment on the formation of calcium ferrite with a perovskite structure and copper ferrite with a mixed spine] structure are demonstrated. Calcium and copper ferrites calcined at low temperatures (450-500 degrees C) are catalytically very active in the water-as shift reaction. CO conversion on calcium and copper ferrites yields a number of by-products. The concentrations of these by-products in the condensate have been determined.
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