Journal
PHYSICAL REVIEW B
Volume 74, Issue 17, Pages -Publisher
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevB.74.174116
Keywords
-
Ask authors/readers for more resources
The structural transitions of the pyrochlore, Cd2Nb2O7, at pressures up to 32.5 GPa have been investigated by in situ Raman scattering and angle-dispersive x-ray diffraction (ADXRD) methods. The x-ray diffraction results reveal that small amounts (similar to 7%) of metallic cadmium form by chemical decomposition at pressures greater than 4 GPa. Both Raman and XRD results indicate that a pressure-induced structural distortion from pyrochlore to defect fluorite occurs in pyrochlore Cd2Nb2O7 at pressures of 12-14 GPa. Subsequently, a new high-pressure phase formed and the phase transition was complete at similar to 27 GPa. The high-pressure phase is either monoclinic or orthorhombic and transforms to either the pyrochlore (or defect fluorite) structure or the amorphous state when quenched to ambient conditions. Energy dispersive spectroscopy (EDS) analysis and high-resolution transmission electron microscopy (HRTEM) observation of the quenched sample confirmed the Cd loss and resulting mixture of ordered pyrochlore, defect fluorite, high-pressure phase, as well as amorphous domains.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available