Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 128, Issue 44, Pages 14337-14340Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja064461h
Keywords
-
Categories
Ask authors/readers for more resources
Newly designed norbornene-appended hexabenzocoronene 1 self-assembles, upon diffusion of an Et2O vapor into its CH2Cl2 solution, to form either graphitic nanocoils or nanotubes, depending on the self-assembling conditions. The coiled assembly, selectively formed at 15 degrees C, is a kinetic intermediate for the tubular assembly and transforms into nanotubes on standing at 25 degrees C. However, post-ring-opening metathesis polymerization of the norbornene pendants of 1 enhances the thermal stability of the coiled assembly as well as the tubular one and disables a thermodynamic coil-to-tube transition. The polymerized nanocoils show an electroconductivity of 1 x 10(-4) S cm(-1) upon doping with I-2, while the nonpolymerized nanocoils are disrupted upon being doped.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available